Cubic KTi2(PO4)3 as electrode materials for sodium-ion batteries

J Colloid Interface Sci. 2016 Dec 1:483:67-72. doi: 10.1016/j.jcis.2016.08.007. Epub 2016 Aug 3.

Abstract

A novel cubic KTi2(PO4)3 is successfully synthesized via a facile hydrothermal method combined with a subsequent annealing treatment and further used as electrode material for sodium-ion batteries for the first time. For comparison, carbon-coated KTi2(PO4)3 obtained by a normal cane sugar-assisted method reveals superior electrochemical performances in sodium-ion battery. Besides of the high coulombic efficiency of nearly 100% after 100 cycles, a stable capacity of 112mAhg(-1) can be achieved at 0.5C after 100 cycles, and still maintains to 105mAhg(-1) after 500 cycles with capacity retention of approximately 90%.

Keywords: Cubic; Cycling stability; Hydrothermal method; Sodium-ion batteries.