Wear studies on ZrO2-filled PEEK as coating bearing materials for artificial cervical discs of Ti6Al4V

Mater Sci Eng C Mater Biol Appl. 2016 Dec 1:69:985-94. doi: 10.1016/j.msec.2016.08.007. Epub 2016 Aug 4.

Abstract

Polyetheretherketone (PEEK) and its composite coatings are believed to be the potential candidates' bio-implant materials. However, these coatings have not yet been used on the surface of titanium-based orthopedics and joint products and very few investigations on the tribological characteristics could be found in the published literature till date. In this study, the wettabilities, composition and micro-hardness were characterized using contact angle measurement, scanning electron microscopy (SEM) and hardness tester. The tribological tests were conducted using a ball-on-disc contact pair under 25% newborn calf serum (NCS) lubricated condition. For comparison, bare Ti6Al4V was studied. The obtained results revealed that those PEEK/ZrO2 composite coatings could improve the tribological properties of Ti6Al4V significantly. Adhesive wear and mild abrasive wear might be the dominant wear and failure mechanisms for PEEK/ZrO2 composite coatings in NCS lubricated condition. After comprehensive evaluation in the present study, 5wt.% ZrO2 nanoparticles filled PEEK coating displayed the optimum tribological characteristics and could be taken as a potential candidate for the bearing material of artificial cervical disc.

Keywords: Artificial cervical disc; Coating; PEEK; Wear; Zirconia.

MeSH terms

  • Alloys
  • Benzophenones
  • Cervical Vertebrae / drug effects*
  • Coated Materials, Biocompatible / chemistry*
  • Friction
  • Hardness
  • Intervertebral Disc / drug effects*
  • Ketones / chemistry*
  • Materials Testing
  • Microscopy, Electron, Scanning
  • Polyethylene Glycols / chemistry*
  • Polymers
  • Spectrometry, X-Ray Emission
  • Titanium / pharmacology*
  • Zirconium / chemistry*

Substances

  • Alloys
  • Benzophenones
  • Coated Materials, Biocompatible
  • Ketones
  • Polymers
  • titanium alloy (TiAl6V4)
  • polyetheretherketone
  • Polyethylene Glycols
  • Zirconium
  • Titanium
  • zirconium oxide