Preparation of bioactive β-tricalcium phosphate microspheres as bone graft substitute materials

Mater Sci Eng C Mater Biol Appl. 2017 Jan 1;70(Pt 2):1200-1205. doi: 10.1016/j.msec.2016.03.040. Epub 2016 Mar 23.

Abstract

In this study, β-tricalcium phosphate (Ca3PO4, β-TCP) microspheres with different diameters were fabricated via a solid-in-oil-in-water (S/O/W) emulsion method. After soaking in simulated body fluid (SBF), the fabricated β-TCP microspheres were fully covered with a new bone-like apatite layer; subsequent analysis suggested that the microspheres have excellent bioactivity properties, specifically in inducing apatite deposition. The calcium release profiles of the microspheres were tested in pH7.4 Tris-HCl buffer, and results demonstrated that the Ca2+ continually released from microspheres during the two-week test period. We then co-cultured bone marrow stem cells (BMSCs) in vitro with β-TCP microspheres, and performed SEM and confocal microscope analyses to find that β-TCP microspheres efficiently promoted BMSC attachment and bone-related gene expression. The co-cultured BMSCs and microspheres were successfully implanted subcutaneously into nude mice for 8weeks. The H&E neo-tissue staining results showed that abundant new bone-like structures had formed between the β-TCP microspheres, implying that β-TCP microspheres used as a cell carrier and bone graft substitute material show highly promising potential application for irregular-shaped bone defect regeneration.

Keywords: Bone formation; Cell delivery; Microspheres; β-Tricalcium phosphate.

MeSH terms

  • Animals
  • Biocompatible Materials / pharmacology*
  • Bone Marrow Cells / cytology
  • Bone Marrow Cells / drug effects
  • Bone Marrow Cells / metabolism
  • Bone Substitutes / pharmacology*
  • Bone Transplantation*
  • Calcium / analysis
  • Calcium Phosphates / pharmacology*
  • Cell Differentiation / drug effects
  • Coculture Techniques
  • Female
  • Gene Expression Regulation / drug effects
  • Humans
  • Materials Testing
  • Mice, Nude
  • Microspheres*
  • Osteogenesis / drug effects
  • Spectroscopy, Fourier Transform Infrared
  • Stem Cells / cytology
  • Stem Cells / drug effects
  • Stem Cells / metabolism
  • Surface Properties
  • X-Ray Diffraction

Substances

  • Biocompatible Materials
  • Bone Substitutes
  • Calcium Phosphates
  • beta-tricalcium phosphate
  • Calcium