A bifunctional cationic porous organic polymer based on a Salen-(Al) metalloligand for the cycloaddition of carbon dioxide to produce cyclic carbonates

Tao-Tao Liu; Jun Liang; Yuan-Biao Huang; Rong Cao

doi:10.1039/c6cc07662a

A bifunctional cationic porous organic polymer based on a Salen-(Al) metalloligand for the cycloaddition of carbon dioxide to produce cyclic carbonates

Chem Commun (Camb). 2016 Nov 3;52(90):13288-13291. doi: 10.1039/c6cc07662a.

Authors

Tao-Tao Liu¹, Jun Liang², Yuan-Biao Huang², Rong Cao²

Affiliations

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter University of Chinese Academy of Sciences Fujian, Fuzhou, 350002, P. R. China. [email protected] [email protected] and University of the Chinese Academy of Sciences, Beijing, 100049, China.
² State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter University of Chinese Academy of Sciences Fujian, Fuzhou, 350002, P. R. China. [email protected] [email protected].

PMID: 27779263
DOI: 10.1039/c6cc07662a

Abstract

A bifunctional cationic porous organic polymer based on a Salen-(Al) metalloligand (Al-CPOP) containing imidazolium functionality exhibited enhanced activity and good recyclability in the cycloaddition of carbon dioxide to produce cyclic carbonates without the addition of co-catalysts at atmospheric pressure.