Cellulose bearing Schiff base and carboxylic acid chelating groups: a low cost and green adsorbent for heavy metal ion removal from aqueous solution

Water Sci Technol. 2016 Oct;74(8):1780-1792. doi: 10.2166/wst.2016.296.

Abstract

Chemically modified cellulose bearing metal binding sites like Schiff base and carboxylic acid groups was synthesized and characterized through Fourier transform infrared and solid state 13C-nuclear magnetic resonance (NMR) analysis. The chemically modified cellulose (Cell-PA) adsorbent was examined for its metal ion uptake ability for Cu(II) and Pb(II) ions from aqueous solution. Kinetic and isotherm studies were carried out under optimum conditions. Pseudo-second-order kinetics and Langmuir isotherm fit well with the experimental data. Thermodynamic studies were also performed along with adsorption regeneration performance studies. The adsorbent (Cell-PA) shows high potential for the removal of Cu(II) and Pb(II) metal ions, and it shows antibacterial activity towards selected microorganisms.

MeSH terms

  • Adsorption
  • Anti-Bacterial Agents / analysis
  • Carboxylic Acids / chemistry*
  • Cellulose / chemistry*
  • Chelating Agents*
  • Metals, Heavy / chemistry*
  • Schiff Bases / chemistry
  • Waste Disposal, Fluid / economics
  • Waste Disposal, Fluid / methods*
  • Water Pollutants, Chemical / chemistry*

Substances

  • Anti-Bacterial Agents
  • Carboxylic Acids
  • Chelating Agents
  • Metals, Heavy
  • Schiff Bases
  • Water Pollutants, Chemical
  • Cellulose