Nitrogen-Doped Mesoporous Carbon-Encapsulated MoO2 Nanobelts as a High-Capacity and Stable Host for Lithium-Ion Storage

Chem Asian J. 2017 Jan 3;12(1):36-40. doi: 10.1002/asia.201601521. Epub 2016 Dec 5.

Abstract

N-doped mesoporous carbon-capped MoO2 nanobelts (designated as MoO2 @NC) were synthesized and applied to lithium-ion storage. Owing to the stable core-shell structural framework and conductive mesoporous carbon matrix, the as-prepared MoO2 @NC shows a high specific capacity of around 700 mA h g-1 at a current of 0.5 A g-1 , excellent cycling stability up to 100 cycles, and superior rate performance. The N-doped mesoporous carbon can greatly improve the conductivity and provide uninhibited conducting pathways for fast charge transfer and transport. Moreover, the core-shell structure improved the structural integrity, leading to a high stability during the cycling process. All of these merits make the MoO2 @NC to be a suitable and promising material for lithium ion battery.

Keywords: core-shell structures; lithium-ion batteries; mesoporous N-doped carbon; molybdenum dioxide; polypyrrole.