Emission of volatile organic compounds from domestic coal stove with the actual alternation of flaming and smoldering combustion processes

Volatile organic compounds (VOCs) emissions from the chimney of a prevailing domestic stove fuelled with raw bituminous coal were measured under flaming and smoldering combustion processes in a farmer's house. The results indicated that the concentrations of VOCs quickly increased after the coal loading and achieved their peak values in a few minutes. The peak concentrations of the VOCs under the smoldering combustion process were significantly higher than those under the flaming combustion process. Alkanes accounted for the largest proportion (43.05%) under the smoldering combustion, followed by aromatics (28.86%), alkenes (21.91%), carbonyls (5.81%) and acetylene (0.37%). The emission factors of the total VOCs under the smoldering combustion processes (5402.9 ± 2031.8 mg kg^-1) were nearly one order of magnitude greater than those under the flaming combustion processes (559.2 ± 385.9 mg kg^-1). Based on the VOCs emission factors obtained in this study and the regional domestic coal consumption, the total VOCs emissions from domestic coal stoves was roughly estimated to be 1.25 × 10⁸ kg a^-1 in the Beijing-Tianjin-Hebei region.