Controlled Encapsulation of Functional Organic Molecules within Metal-Organic Frameworks: In Situ Crystalline Structure Transformation

Adv Mater. 2017 Mar;29(12). doi: 10.1002/adma.201606290. Epub 2017 Jan 23.

Abstract

Functional organic molecules/metal-organic frameworks composites can be obtained by in situ crystalline structure transformation from ZIF-L to ZIF-8-L under double solvent conditions. Interestingly, the as-prepared molecules/ZIF-8-L composites with the leaf-like morphology exhibit good fluorescence properties and size selectivity in fluorescent quenchers due to the molecular sieving effect of the well-defined microporous ZIF-8-L.

Keywords: composites; fluorescent molecules; metal-organic frameworks; selectivity; structure transformation.