Lysosome-Targeting Fluorogenic Probe for Cathepsin B Imaging in Living Cells

Anal Chem. 2016 Dec 20;88(24):12403-12410. doi: 10.1021/acs.analchem.6b03717. Epub 2016 Nov 30.

Abstract

Cathepsin B (CTB) is a lysosomal protease which has been recognized as a promising biomarker for many malignant tumors, and accurate detection of its activity is important in early diagnosis of cancers and predicting metastasis. Herein, we reported a lysosome-targeting fluorogenic small-molecule probe for fluorescence imaging of lysosomal CTB in living cancer cells by incorporating a CTB-recognitive peptide substrate Cbz-Lys-Lys-p-aminobenzyl alcohol (Cbz-Lys-Lys-PABA) and a lysosome locating group morpholine. We demonstrated that the probe could be efficiently activated by CTB to generate ∼73-fold enhancement in fluorescence under acidic lysosomal environment (pH 4.5-6.0), allowing for high sensitivity and specificity to detect CTB. Fluorescence imaging results showed selective accumulation and fluorescence turn-on in the lysosomes of cancer cells, which were capable of reporting on lysosomal CTB activity in cancer cells and normal tissue cells. This study highlights the potential of using a lysosome-targeting group to design a sensitive and specific fluorogenic probe for fluorescence imaging of lysosomal CTB in living cells.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzyl Alcohols / chemistry
  • Cathepsin B / analysis*
  • Cell Line, Tumor
  • Fluorescence
  • Fluorescent Dyes / chemistry*
  • HeLa Cells
  • Humans
  • Lysosomes / chemistry*
  • Lysosomes / pathology
  • Microscopy, Fluorescence / methods
  • Neoplasms / chemistry
  • Neoplasms / pathology
  • Oligopeptides / chemistry*
  • Optical Imaging / methods

Substances

  • Benzyl Alcohols
  • Fluorescent Dyes
  • Oligopeptides
  • 4-aminobenzyl alcohol
  • Cathepsin B