Green synthesis of Ag/Fe(3)O(4) nanocomposite using Euphorbia peplus Linn leaf extract and evaluation of its catalytic activity

J Colloid Interface Sci. 2017 Jul 1:497:1-13. doi: 10.1016/j.jcis.2017.02.037. Epub 2017 Feb 22.

Abstract

In this work, the Ag/Fe3O4 nanocomposite was prepared by Euphorbia peplus Linn (L.) leaf extract as a suitable reducing source and stabilizing agent. The green synthesized nanocomposite was characterized using X-ray diffraction analysis (XRD), field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM) images, energy-dispersive X-ray spectroscopy (EDS) and FT-IR spectroscopy. TEM analysis of Ag/Fe3O4 nanocomposite showed the spherical shape nanoparticles (NPs) with an average size of 5-10nm. The Ag/Fe3O4 nanocomposite then was used as a magnetically recoverable catalyst for the [2+3] cycloaddition of arylcyanamides and sodium azide in high yields and short reaction times without formation of hydrazoic acid (HN3). Also it can be easily recovered via applying of external magnetic field and reused several times without significant loss of activity.

Keywords: Ag/Fe(3)O(4); Arylaminotetrazoles; Euphorbia peplus L.; Green synthesis; Heterogeneous catalyst.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Euphorbia / chemistry*
  • Green Chemistry Technology*
  • Nanocomposites / chemistry*
  • Nanocomposites / ultrastructure
  • Plant Extracts / chemistry*
  • Plant Leaves / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • X-Ray Diffraction

Substances

  • Plant Extracts