Heterologous Expression, Purification, and Functional Analysis of Plasmodium falciparum Phosphatidylinositol 3'-Kinase

Biochemistry. 2017 Aug 22;56(33):4335-4345. doi: 10.1021/acs.biochem.7b00416. Epub 2017 Aug 8.

Abstract

The Plasmodium falciparum malarial parasite genome appears to encode one and only one phosphatidylinositol 3'-kinase (PI3K), and sequence analysis suggests that the enzyme is a "class III"- or "Vps34"-type PI3K. PfVps34 has generated excitement as a possible druggable target and potentially a key target of artemisinin-based antimalarials. In this study, we optimize the PfVps34 gene for heterologous expression in yeast, purify the protein to homogeneity, use a recently validated quantitative assay for phosphatidylinositol 3'-phosphate production from phosphatidylinositol ( Hassett et al., companion paper; DOI 10.1021/acs.biochem.7b00416 ) to quantify activity and drug inhibition of that activity, and investigate the importance of key residues in the enzyme's catalytic and "N-lobe" domains. Data suggest that PfVps34 is indeed inhibited by artemisinin and related drugs but only under conditions that cleave the drugs' endoperoxide bridge to generate reactive alkylating agents.

MeSH terms

  • Class III Phosphatidylinositol 3-Kinases* / biosynthesis
  • Class III Phosphatidylinositol 3-Kinases* / chemistry
  • Class III Phosphatidylinositol 3-Kinases* / genetics
  • Class III Phosphatidylinositol 3-Kinases* / isolation & purification
  • Cloning, Molecular*
  • Gene Expression*
  • Plasmodium falciparum* / enzymology
  • Plasmodium falciparum* / genetics
  • Protein Domains
  • Protozoan Proteins* / biosynthesis
  • Protozoan Proteins* / chemistry
  • Protozoan Proteins* / isolation & purification
  • Recombinant Proteins / biosynthesis
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Recombinant Proteins / isolation & purification
  • Saccharomyces cerevisiae / genetics
  • Saccharomyces cerevisiae / metabolism

Substances

  • Protozoan Proteins
  • Recombinant Proteins
  • Class III Phosphatidylinositol 3-Kinases