Synthesis-Free Phase-Selective Gelator for Oil-Spill Remediation

ACS Appl Mater Interfaces. 2017 Oct 4;9(39):33549-33553. doi: 10.1021/acsami.7b10009. Epub 2017 Sep 20.

Abstract

A new deep eutectic solvent (DES) was developed as a phase-selective gelator for oil-spill remediation. The newly designed nonionic DES is based on a combination of an amide (N-methylacetamide) and a long chain carboxylic acid (lauric acid) and does not require any synthetic procedure besides mixing. Our studies show that the DES works as gelator by forming a gel between lauric acid and the hydrocarbon, whereas the amide serves to form the DES and dissolves in water during the gelation process. In addition, the DES material has gelation properties comparable to those considered as state-of-the-art. Overall, the newly developed material shows a promising future in oil recovery methodologies.

Keywords: DES lauric acid and N-methylacetamide; N-methylacetamide; deep eutectic solvent; lauric acid; oil gelation; oil-spill remediation; phase-selective gelator.