Simultaneous removal of cadmium, zinc and manganese using electrocoagulation: Influence of operating parameters and electrolyte nature

In the present study, the influence of operating parameters and electrolyte nature on the simultaneous removal of toxic metals (cadmium, zinc and manganese) from synthetic smelting wastewater by batch electrocoagulation was investigated. This wastewater contained high concentrations of anion-cation electrolytes. Results indicated that the efficiency of heavy metals removal can be enhanced by increasing the solution pH and current density. The Fe-Fe electrode combination is more effective than the other combinations (Al-Al, Al-Fe and Fe-Al). The interaction of heavy metal ions showed that the increase of initial Zn²⁺ concentration adversely affects on Cd²⁺ removal. In addition, the single chloride system exhibits the optimum removal efficiency on Mn²⁺. Single sulfate and binary anion systems exert a more positive effect on Cd²⁺ and Zn²⁺ removal because of the stronger charge neutralization and destabilization of iron hydroxide flocs. Increases of Ca²⁺ and Mg²⁺ ions exert a significant negative effect on metal removal. However, the addition of a small amount of sodium chloride into a high sulfate and hardness solution can accelerate the removal of heavy metals. Finally, the sludge samples generated from electrocoagulation were characterized by XRD and SEM-EDS analyses.