A Multiheteroatom [3,3]-Sigmatropic Rearrangement: Disproportionative Entries into 2-(N-Heteroaryl)methyl Phosphates and α-Keto Phosphates

Yongkang Yang; Chen Qu; Xiaolan Chen; Kai Sun; Lingbo Qu; Wenzhu Bi; Hao Hu; Rui Li; Chunfeng Jing; Donghui Wei; Shengkai Wei; Yuanqiang Sun; Hui Liu; Yufen Zhao

doi:10.1021/acs.orglett.7b02852

A Multiheteroatom [3,3]-Sigmatropic Rearrangement: Disproportionative Entries into 2-(N-Heteroaryl)methyl Phosphates and α-Keto Phosphates

Org Lett. 2017 Nov 3;19(21):5864-5867. doi: 10.1021/acs.orglett.7b02852.

Authors

Yongkang Yang^{1

2}, Chen Qu³, Xiaolan Chen¹, Kai Sun¹, Lingbo Qu¹, Wenzhu Bi¹, Hao Hu¹, Rui Li¹, Chunfeng Jing¹, Donghui Wei¹, Shengkai Wei¹, Yuanqiang Sun¹, Hui Liu¹, Yufen Zhao^{1

2}

Affiliations

¹ College of Chemistry and Molecular Engineering, Zhengzhou University , Zhengzhou 450052, China.
² Department of Chemistry, Xiamen University , Xiamen 361005, China.
³ Department of Chemical and Biomolecular Engineering, University of Notre Dame , Notre Dame, Indiana 46556, United States.

PMID: 29072069
DOI: 10.1021/acs.orglett.7b02852

Abstract

A novel multiheteroatom (N, O and P) [3,3]-sigmatropic rearrangement is disclosed, based on two important types of organophosphates, 2-(N-heteroaryl) methyl phosphates and α-keto phosphates, being accessed smoothly and efficiently.

Publication types

Research Support, Non-U.S. Gov't