Structural characterization and macrophage activation of a hetero-galactan isolated from Flammulina velutipes

Carbohydr Polym. 2018 Mar 1:183:207-218. doi: 10.1016/j.carbpol.2017.12.017. Epub 2017 Dec 11.

Abstract

We isolated and purified a new polysaccharide (WFVP-N-b1) with a molecular weight of 20 kDa from Flammulina velutipes. Results showed that WFVP-N-b1 is composed of an α (1 → 6)-linked D-galactan backbone and branched at the O-2 of its Galp residues by an α-D-(1 → 6)-linked Manp attached to t-β-D-Glcp or t-α-D-Fucp side chains. WFVP-N-b1 can significantly induce cytokines secretion and release of toxic molecules. On a cellular level, WFVP-N-b1 is recognized by Toll-like receptor 4 (TLR4). Thereby, the hetero-galactan increased the phosphorylation of mitogen-activated protein kinases (MAPKs) and Akt, promoted degradation of IκB-α and the nuclear translocation of the NF-κB p65 subunit. Importantly, our results indicate that WFVP-N-b1 activated macrophage is mediated by autophagy, as blockade of WFVP-N-b1-induced autophagy by Baf-A1 significantly decreases macrophage activation. This is the first report that hetero-galactan-induced macrophage activation is mediated by autophagy. Collectively, WFVP-N-b1 activated RAW264.7 cells through MAPKs, autophagy, and Akt/NF-κB signaling pathways via TLR4 receptor.

Keywords: Akt/NF-κB; Autophagy; Flammulina velutipes; Hetero-galactan; MAPKs; Macrophage.

MeSH terms

  • Animals
  • Anti-Inflammatory Agents / chemistry*
  • Anti-Inflammatory Agents / pharmacology
  • Autophagy
  • Cell Line
  • Cytokines / genetics
  • Cytokines / metabolism
  • Female
  • Flammulina / chemistry*
  • Fungal Polysaccharides / chemistry*
  • Fungal Polysaccharides / pharmacology
  • Galactans / chemistry*
  • Galactans / pharmacology
  • MAP Kinase Signaling System
  • Macrophage Activation*
  • Macrophages / drug effects
  • Macrophages / immunology
  • Mice
  • Mice, Inbred BALB C
  • NF-kappa B / metabolism
  • Nitric Oxide / metabolism
  • Phagocytosis
  • Proto-Oncogene Proteins c-akt / metabolism
  • Reactive Oxygen Species / metabolism
  • Toll-Like Receptor 4 / metabolism

Substances

  • Anti-Inflammatory Agents
  • Cytokines
  • Fungal Polysaccharides
  • Galactans
  • NF-kappa B
  • Reactive Oxygen Species
  • Toll-Like Receptor 4
  • Nitric Oxide
  • Proto-Oncogene Proteins c-akt