Metabolism of SKLB-TB1001, a Potent Antituberculosis Agent, in Animals

Antimicrob Agents Chemother. 2018 Jun 26;62(7):e02375-17. doi: 10.1128/AAC.02375-17. Print 2018 Jul.

Abstract

Tuberculosis is a major global health problem, and the emergence of multidrug-resistant and extensively drug-resistant strains has increased the difficulty of treating this disease. Among the novel antituberculosis drugs in the pipeline, decaprenylphosphoryl-beta-d-ribose-2-epimerase (DprE1) inhibitors such as BTZ043 and pBTZ169 exhibited extraordinary antituberculosis potency. Here, the metabolites of the new DprE1 inhibitor SKLB-TB1001 in vivo and its inhibition of cytochrome P450 isoforms and plasma protein binding (PPB) in vitro were studied. The results showed that rapid transformation and high PPB resulted in inadequate exposure in vivo and thus led to the moderate potency of SKLB-TB1001 in vivo This study provided explanations for the discrepant potency of this scaffold in vivo and in vitro Meanwhile, it also provides a rationale for lead optimization of this very promising scaffold of antituberculosis agents to prevent them from being metabolized, thus improving their exposure in vivo.

Keywords: DprE1; MDR-TB; drug metabolism; tuberculosis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antitubercular Agents / chemistry
  • Antitubercular Agents / pharmacokinetics*
  • Bacterial Proteins / genetics
  • Bacterial Proteins / metabolism*
  • Mice
  • Molecular Structure
  • Rats
  • Rats, Sprague-Dawley
  • Structure-Activity Relationship
  • Tandem Mass Spectrometry
  • Tuberculosis / drug therapy*
  • Tuberculosis / metabolism

Substances

  • Antitubercular Agents
  • Bacterial Proteins