Palladium nanoparticle-decorated 2-D graphene oxide for effective photodynamic and photothermal therapy of prostate solid tumors

Colloids Surf B Biointerfaces. 2018 Sep 1:169:429-437. doi: 10.1016/j.colsurfb.2018.05.051. Epub 2018 May 23.

Abstract

Intratumoral injection of nanoparticles is a viable alternative for treating solid tumors. In this study, we used intratumorally-injected palladium nanoparticle (Pd NP)-decorated graphene oxide (GO) (GO-Pd NPs) for the treatment of solid prostate tumors. GO was synthesized using the modified Hummer's method and GO-Pd NPs were prepared using the one pot synthesis method. Studies on physicochemical characterization and in vitro/in vivo anticancer properties were performed using GO-Pd NPs. Successful preparation of GO-Pd NPs was confirmed by transmission electron microscopy, Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. Compared to GO or Pd NPs alone, GO-Pd NPs showed higher cytotoxic effects in prostate cancer 3 (PC3) cells. Irradiation of treated cells with near infrared (NIR) laser considerably enhanced apoptosis induced by synergistic photothermal effect and reactive oxygen species (ROS) generation. Intratumorally-injected GO-Pd NPs showed promising in vivo localized distribution, photothermal ablation, and anti-tumor effects in the PC3 xenograft mouse model. Furthermore, the minimal organ toxicity of GO-Pd NPs was an added advantage. Hence, GO-Pd NPs could be a potential formulation for localized treatment of prostate solid tumors.

Keywords: Graphene oxide; Palladium nanoparticles; Photothermal therapy; Prostate cancer; Reactive oxygen species.

MeSH terms

  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / pharmacology*
  • Cell Cycle / drug effects
  • Cell Proliferation / drug effects
  • Cell Survival / drug effects
  • Drug Screening Assays, Antitumor
  • Graphite / chemistry*
  • Humans
  • Male
  • Metal Nanoparticles / chemistry*
  • PC-3 Cells
  • Palladium / chemistry
  • Palladium / pharmacology*
  • Particle Size
  • Photochemotherapy*
  • Prostatic Neoplasms / drug therapy*
  • Prostatic Neoplasms / pathology
  • Surface Properties

Substances

  • Antineoplastic Agents
  • graphene oxide
  • Palladium
  • Graphite