Abstract
A modular and practical route to versatile cyano-1,3-dienes by a sequence involving deconjugative alkylation and "Tsuji-Saegusa-Ito oxidation" is reported. In this letter, the versatility of the products is also explored, including a route to benzochromene scaffolds common to many natural products.
Publication types
-
Research Support, N.I.H., Extramural
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Alkadienes / chemistry
-
Alkylation
-
Benzopyrans / chemical synthesis*
-
Catalysis
-
Isomerism
-
Molecular Structure
-
Nitriles / chemistry
-
Organometallic Compounds / chemistry
-
Oxidation-Reduction
-
Palladium / chemistry
Substances
-
Alkadienes
-
Benzopyrans
-
Nitriles
-
Organometallic Compounds
-
Palladium