5,10-methenyltetrahydrofolate synthetase deficiency causes a neurometabolic disorder associated with microcephaly, epilepsy, and cerebral hypomyelination

Mol Genet Metab. 2018 Sep;125(1-2):118-126. doi: 10.1016/j.ymgme.2018.06.006. Epub 2018 Jun 15.

Abstract

Folate metabolism in the brain is critically important and serves a number of vital roles in nucleotide synthesis, single carbon metabolism/methylation, amino acid metabolism, and mitochondrial translation. Genetic defects in almost every enzyme of folate metabolism have been reported to date, and most have neurological sequelae. We report 2 patients presenting with a neurometabolic disorder associated with biallelic variants in the MTHFS gene, encoding 5,10-methenyltetrahydrofolate synthetase. Both patients presented with microcephaly, short stature, severe global developmental delay, progressive spasticity, epilepsy, and cerebral hypomyelination. Baseline CSF 5-methyltetrahydrolate (5-MTHF) levels were in the low-normal range. The first patient was treated with folinic acid, which resulted in worsening cerebral folate deficiency. Treatment in this patient with a combination of oral L-5-methyltetrahydrofolate and intramuscular methylcobalamin was able to increase CSF 5-MTHF levels, was well tolerated over a 4 month period, and resulted in subjective mild improvements in functioning. Measurement of MTHFS enzyme activity in fibroblasts confirmed reduced activity. The direct substrate of the MTHFS reaction, 5-formyl-THF, was elevated 30-fold in patient fibroblasts compared to control, supporting the hypothesis that the pathophysiology of this disorder is a manifestation of toxicity from this metabolite.

Keywords: 5,10-methenyltetrahydrofolate synthetase; Folate; Folinic acid; Neurodegeneration; Neurometabolism.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Amino Acid Transport Systems, Acidic / cerebrospinal fluid
  • Amino Acid Transport Systems, Acidic / deficiency*
  • Amino Acid Transport Systems, Acidic / genetics
  • Amino Acid Transport Systems, Acidic / metabolism
  • Antiporters / cerebrospinal fluid
  • Antiporters / deficiency*
  • Antiporters / genetics
  • Antiporters / metabolism
  • Brain / metabolism
  • Brain / pathology
  • Carbon-Nitrogen Ligases / cerebrospinal fluid
  • Carbon-Nitrogen Ligases / deficiency
  • Carbon-Nitrogen Ligases / genetics*
  • Carbon-Nitrogen Ligases / metabolism
  • Epilepsy / cerebrospinal fluid
  • Epilepsy / complications
  • Epilepsy / genetics*
  • Epilepsy / pathology
  • Female
  • Folate Receptor 1 / deficiency
  • Hereditary Central Nervous System Demyelinating Diseases / cerebrospinal fluid
  • Hereditary Central Nervous System Demyelinating Diseases / complications
  • Hereditary Central Nervous System Demyelinating Diseases / genetics*
  • Hereditary Central Nervous System Demyelinating Diseases / metabolism
  • Humans
  • Male
  • Metabolic Diseases / cerebrospinal fluid
  • Metabolic Diseases / complications
  • Metabolic Diseases / genetics
  • Metabolic Diseases / pathology
  • Microcephaly / cerebrospinal fluid
  • Microcephaly / complications
  • Microcephaly / genetics*
  • Microcephaly / pathology
  • Mitochondrial Diseases / cerebrospinal fluid
  • Mitochondrial Diseases / complications
  • Mitochondrial Diseases / genetics*
  • Mitochondrial Diseases / metabolism
  • Nervous System Malformations / cerebrospinal fluid
  • Nervous System Malformations / complications
  • Nervous System Malformations / genetics
  • Nervous System Malformations / metabolism
  • Neuroaxonal Dystrophies
  • Psychomotor Disorders / cerebrospinal fluid
  • Psychomotor Disorders / complications
  • Psychomotor Disorders / genetics*
  • Psychomotor Disorders / metabolism
  • Tetrahydrofolates / cerebrospinal fluid
  • Tetrahydrofolates / metabolism

Substances

  • Amino Acid Transport Systems, Acidic
  • Antiporters
  • Folate Receptor 1
  • Tetrahydrofolates
  • Carbon-Nitrogen Ligases
  • 5,10-methenyltetrahydrofolate synthetase
  • 5-methyltetrahydrofolate

Supplementary concepts

  • Hypomyelination, Global Cerebral
  • Neurodegeneration Due To Cerebral Folate Transport Deficiency