Microwave-Assisted Facile Synthesis of Eu(OH)3 Nanoclusters with Pro-Proliferative Activity Mediated by miR-199a-3p

ACS Appl Mater Interfaces. 2018 Sep 19;10(37):31044-31053. doi: 10.1021/acsami.8b10543. Epub 2018 Sep 6.

Abstract

As a pharmaceutical excipient, dextran serves as an efficient ligand for stabilizing some clinically available inorganic nanomaterials such as iron oxide nanocrystals. Herein, dextran-capped nanosized europium(III) hydroxides [Eu(OH)3] nanoclusters (NCs) composed of 5 nm Eu(OH)3 nanoparticles have been large-scale synthesized via a microwave-accelerated hydrothermal reaction. The as-synthesized Eu(OH)3 NCs exhibited excellent physiological stability and biocompatibility both in vitro and in vivo and possessed considerable pro-proliferative activities in human umbilical vein endothelial cells (HUVECs). To investigate the epigenetic modulation of Eu(OH)3 NCs-elicited proliferation, the newly developed high-throughput next generation sequencing technology was employed herein. As a result, we have screened 371 dysregulated miRNAs in Eu(OH)3 NCs-treated HUVECs and obtained 26 potentially functional miRNAs in promoting cell proliferation. Furthermore, upregulated miR-199a-3p was predicted, validated, and eventually confirmed to be a crucial modulator in the pro-proliferative activity of Eu(OH)3 NCs by targeting zinc fingers and homeoboxes protein 1 (ZHX1). Importantly, these findings provide potential therapeutic strategy for ischemic heart/limb diseases and tissue regeneration by combination of nanomedicine and gene therapy with Eu(OH)3 NCs and miR-199a-3p-ZHX1 axis modulation.

Keywords: Eu(OH)3 nanoclusters; cell proliferation; miR-199a-3p; microwave-assisted synthesis; next generation sequencing.

MeSH terms

  • Cell Proliferation / drug effects
  • Human Umbilical Vein Endothelial Cells / drug effects
  • Humans
  • MicroRNAs / metabolism*
  • Microwaves*
  • Nanoparticles / chemistry*

Substances

  • MicroRNAs
  • mirn199 microRNA, human