Light-Induced Activation of c-Met Signalling by Photocontrolled DNA Assembly

Chemistry. 2018 Oct 26;24(60):15988-15992. doi: 10.1002/chem.201803868. Epub 2018 Oct 4.

Abstract

Optical manipulation appears to be a powerful tool for spatiotemporally controlling a variety of cellular functions. Herein, a photocontrolled DNA assembly approach is described which enables light-induced activation of cellular signal transduction by triggering protein dimerization (c-Met signalling in this case). Three kinds of DNA probes are designed, including a pair of receptor recognition probes with adaptors and a blocker probe with a photocleavable linker (PC-linker). By implementing PC-linkers in blocker probes, the designed DNA probes response to light irradiation, which then induces the assembly of receptor recognition probes through adaptor complementing. Consequently, light-mediated DNA assembly promotes the dimerization of c-Met receptors, resulting in activation of c-Met signalling. It is demonstrated that the proposed photocontrolled DNA assembly approach is effective for regulating c-Met signalling and modulating cellular behaviours, such as cell proliferation and migration. Therefore, this simple approach may offer a promising strategy to manipulate cell signalling pathways precisely in living cells.

Keywords: DNA assembly; aptamers; light-induced; living cells; signal transduction.

MeSH terms

  • Aptamers, Nucleotide / chemistry
  • Carbocyanines / chemistry
  • Cell Line, Tumor
  • Cell Membrane
  • Cell Movement
  • Cell Proliferation
  • Cell Survival
  • DNA Probes / chemistry*
  • Fluorescent Dyes / chemistry
  • Humans
  • Light
  • Photochemical Processes
  • Protein Multimerization
  • Proto-Oncogene Proteins c-met / metabolism*
  • Signal Transduction

Substances

  • Aptamers, Nucleotide
  • Carbocyanines
  • DNA Probes
  • Fluorescent Dyes
  • cyanine dye 3
  • cyanine dye 5
  • Proto-Oncogene Proteins c-met