Design of a stretchable DNAzyme for sensitive and multiplexed detection of antibodies

Anal Chim Acta. 2018 Dec 24:1041:102-107. doi: 10.1016/j.aca.2018.08.052. Epub 2018 Aug 29.

Abstract

Advanced methods for developing and applying responsive DNA nanodevices are of great interest. Herein, we report a stretchable DNAzyme that allows simple, multiplexed and sensitive fluorescent detection of antibodies. We find that rigid antibody can tightly stretch soft, antigen-labelled DNAzyme strand and disrupt the hybridization between DNAzyme and its substrate. Based on this finding, we develop a novel strategy to detect antibodies. Due to the robustness and high activity of DNAzyme, this assay can easily detect target as low as 1 ± 0.25 pM and achieve multiplexed detection by using a cocktail of DNAzymes. The proposed assay not only provides a new approach to readily measure antibody, but broadens the application of DNAzyme that is usually employed to detect metal ions or indirectly analyze biomolecules without the cumbersome design.

Keywords: Antibody; Inhibition; Multiplexed detection; Stretchable DNAzyme.

MeSH terms

  • Antibodies / analysis*
  • Antibodies / blood
  • Antibodies / metabolism
  • DNA Primers / chemistry
  • DNA Primers / metabolism
  • DNA, Catalytic / chemistry
  • DNA, Catalytic / metabolism*
  • Digoxigenin / chemistry
  • Fluorescent Dyes / chemistry
  • Humans
  • Limit of Detection
  • Nucleic Acid Hybridization
  • Spectrometry, Fluorescence*
  • Zinc / chemistry

Substances

  • Antibodies
  • DNA Primers
  • DNA, Catalytic
  • Fluorescent Dyes
  • Zinc
  • Digoxigenin