Determination of valence electronic structure of Ni in Ni-B alloy coatings using Kβ-to-Kα X-ray intensity ratios

Appl Radiat Isot. 2019 Feb:144:24-28. doi: 10.1016/j.apradiso.2018.11.009. Epub 2018 Nov 23.

Abstract

In this study, Kβ-to-Kα X-ray intensity ratios of Ni in Ni-B alloy coatings were investigated. These samples were excited by 59.5 keV gamma-rays from a 241Am annular radioactive source. K X-rays emitted by the samples were counted using an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The Kβ-to-Kα X-ray intensity ratios of Ni-B alloys are compared with pure Ni and each other. Deviations between the results were explained by the change in valence electronic structures of Ni in Ni-B alloy coatings.

Keywords: (241)Am source; K X-ray intensity ratios; Ni-B alloy; Valence electronic structure.