Surfactant-assisted synthesis and electrochemical properties of an unprecedented polyoxometalate-based metal-organic nanocaged framework

Xiya Yang; Peipei Zhu; Jing Ren; Yuhao Chen; Xiao Li; Jingquan Sha; Jianzhuang Jiang

doi:10.1039/c8cc08559e

Surfactant-assisted synthesis and electrochemical properties of an unprecedented polyoxometalate-based metal-organic nanocaged framework

Chem Commun (Camb). 2019 Jan 24;55(9):1201-1204. doi: 10.1039/c8cc08559e.

Authors

Xiya Yang¹, Peipei Zhu, Jing Ren, Yuhao Chen, Xiao Li, Jingquan Sha, Jianzhuang Jiang

Affiliation

¹ Key Laboratory of Inorganic Chemistry, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155, P. R. China. [email protected].

PMID: 30534759
DOI: 10.1039/c8cc08559e

Abstract

The first polyoxometalate (POM)-containing nanocage based metal-organic framework (Zn-POMCF) was synthesized by a surfactant-assisted method. In contrast to the Zn-based metal-organic framework (Zn-MOF), the cooperative assembly of POM and a Zn/trz macrocycle gave rise to high stability and good electrochemical ability of the Zn-POMCF in lithium-ion batteries (LIBs).