Parentucellia latifolia subsp. latifolia: A potential source for loganin iridoids by HPLC-ESI-MSn technique

J Pharm Biomed Anal. 2019 Feb 20:165:374-380. doi: 10.1016/j.jpba.2018.12.025. Epub 2018 Dec 17.

Abstract

This study attempts to compare the pharmaceutical potential (antioxidant and key enzyme inhibition of clinical relevance) of organic and aqueous extracts of Parentucellia latifolia (L.) Caruel subsp. latifolia (L.) Caruel as well as phytochemical composition. The phytochemical compounds were evaluated by spectrophotometric methods (for total amounts) and HPLC-ESI-DAD-MSn (for individual compounds). The extracts were screened for antioxidant abilities by in vitro assays. Inhibition effects were also investigated against a set of enzymes linked to major health problems. Generally, the methanol (MeOH) and aqueous extracts displayed higher scavenging abilities on radicals and reductive effects when compared with the ethyl acetate (EtOAc) extract. On the other hand, the EtOAc extract was the most active inhibitor on cholinesterases (1.81-1.88 mg GALAE/g), amylase (0.70 mmol ACAE/g), glucosidase (2.85 mmol ACAE/g) and lipase (33.24 mg OE/g). The highest TPC was observed in the aqueous extract (25.07 mg GAE/g) while MeOH extract possessed the highest level of TFC (44.15 mg RE/g) and TPAC (3.46 mg CE/g). LC-MSn metabolite profiling indicated that loganin and its isomers, rutin, and luteolin-O-hexoside were the most abundant compounds. Our results suggest that P. latifolia may be valuable source of phyto-agents for the management of noncommunicable diseases.

Keywords: Antioxidants; Enzyme inhibition; Flavonoid; Loganin; Parentucellia latifolia; Phenolic.

MeSH terms

  • Antioxidants / isolation & purification*
  • Antioxidants / pharmacology
  • Chromatography, High Pressure Liquid / methods*
  • Enzyme Inhibitors / isolation & purification
  • Enzyme Inhibitors / pharmacology
  • Free Radical Scavengers / isolation & purification
  • Free Radical Scavengers / pharmacology
  • Iridoids / isolation & purification*
  • Iridoids / pharmacology
  • Orobanchaceae / chemistry*
  • Plant Extracts / chemistry
  • Plant Extracts / pharmacology
  • Spectrometry, Mass, Electrospray Ionization / methods

Substances

  • Antioxidants
  • Enzyme Inhibitors
  • Free Radical Scavengers
  • Iridoids
  • Plant Extracts
  • loganin