Structural characterization and in vitro hypoglycemic activity of a glucan from Euryale ferox Salisb. seeds

Carbohydr Polym. 2019 Apr 1:209:363-371. doi: 10.1016/j.carbpol.2019.01.044. Epub 2019 Jan 14.

Abstract

In this research, a polysaccharide fraction (EFSP-1) was obtained from the seeds of Euryale ferox Salisb. by DEAE sepharose FF and Superdex 75 gel chromatography. The average molecular weight (Mw) of EFSP-1 was 8.75 kDa. Monosaccharides composition analysis indicated that EFSP-1 was a glucan. The structure of EFSP-1 was characterized by analysis of FT-IR, GC-MS and NMR, which indicated that the backbone of EFSP-1 was mainly composed of (1→4)-α-D-Glcp with branches substituted at O-6 and terminated with T-α-D-Glcp. Moreover, the hypoglycemic effect of EFSP-1 was investigated by establishing insulin resistance HepG2 and 3T3-L1 cells. The results showed that EFSP-1 could increase glucose consumption by up-regulating the expression of GLUT-4 via activating PI3K/Akt signal pathway in IR cells. Hence, EFSP-1 could be a potential functional food to ameliorate insulin resistance for diabetes therapy.

Keywords: 1-phenyl-3-methyl-5-pyrazolone (PubChem CID: 90474051); 3T3-L1 cells; Acetic anhydride (PubChem CID: 7918); D-arabinose (PubChem CID: 229); D-galactose (PubChem CID: 6036); D-glucose (PubChem CID: 5793); D-mannose (PubChem CID: 18950); Dimethyl sulfoxide (PubChem CID: 679); Euryale feroxseed; Glucan; Glucuronic acid (PubChem CID: 94715); HepG2 cells; Hypoglycemic activity; Insulin resistance; Methyl iodide (PubChem CID: 6328); Pyridine (PubChem CID: 1049); Sodium borohydride (PubChem CID: 4311764); Sodium hydroxide (PubChem CID: 14798); Trifluoroacetic acid (PubChem CID: 6422).

MeSH terms

  • 3T3-L1 Cells
  • Animals
  • Glucans / chemistry*
  • Glucans / pharmacology*
  • Glucose / metabolism
  • Hep G2 Cells
  • Humans
  • Hypoglycemic Agents / chemistry*
  • Hypoglycemic Agents / pharmacology*
  • Insulin Resistance
  • Mice
  • Monosaccharides / analysis
  • Nymphaeaceae / chemistry*
  • Phosphatidylinositol 3-Kinases / metabolism
  • Proto-Oncogene Proteins c-akt / metabolism
  • Seeds / chemistry

Substances

  • Glucans
  • Hypoglycemic Agents
  • Monosaccharides
  • Phosphatidylinositol 3-Kinases
  • Proto-Oncogene Proteins c-akt
  • Glucose