Room temperature hysteretic spin crossover in a new cyanoheterometallic framework

Chem Commun (Camb). 2019 Mar 14;55(23):3359-3362. doi: 10.1039/c8cc10260k.

Abstract

A new iron(ii)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported. This complex exhibits a high reproducibility of the spin transition in many successive thermal cycles, stability of both spin states at room temperature and an attractive operational temperature range.