Detection and quantification of 47 antibiotic residues in farmed European sea bass (Dicentrarchus labrax) using a multi-class and multi-residue UHPLC-MS/MS method

Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2019 Apr;36(4):561-570. doi: 10.1080/19440049.2019.1572229. Epub 2019 Mar 22.

Abstract

In the present study, a multi-class multi-residue method for the simultaneous detection and determination of antibiotics in European sea bass (Dicentrarchus labrax) was developed and validated. The method based on UHPLC-MS/MS proved to be a rapid, highly selective and sensitive tool, requiring minimum sample preparation, for screening and detection of 47 compounds from eight different classes. The validation was performed according to EU regulation 2002/657/EC, proving the method's suitability for application in routine analysis. The method was applied to the analysis of 30 samples of farmed European sea bass purchased in different supermarkets in Portugal. Antibacterial residues were detected in 6 of the 30 analysed samples, namely enrofloxacin and oxytetracycline, in concentrations ranging from 0.1 to 12 µg kg-1.

Keywords: Antibiotics; European sea bass; UHPLC-MS/MS; multi-residue.

MeSH terms

  • Animals
  • Anti-Bacterial Agents / analysis*
  • Bass*
  • Chromatography, High Pressure Liquid
  • Drug Residues / analysis*
  • Fisheries*
  • Portugal
  • Tandem Mass Spectrometry

Substances

  • Anti-Bacterial Agents