Tacrolimus-loaded methoxy poly(ethylene glycol)-block-poly(D,L)-lactic-co-glycolic acid micelles self-assembled in aqueous solution for treating cornea immune rejection after allogenic penetrating keratoplasty in rats

Eur J Pharm Sci. 2019 May 15:133:104-114. doi: 10.1016/j.ejps.2019.03.023. Epub 2019 Mar 27.

Abstract

This study aimed to develop a stable and biodegradable tacrolimus loaded nanocarrier that enhanced tacrolimus corneal penetration and delivered in a sustained manner, thus to create a promising treatment to prevent immune rejection after corneal allografts. Spherical tacrolimus loaded methoxy poly (ethylene glycol)-block-poly (D,L)-lactic-co-glycolic acid (mPEG-b-PLGA) micelles with a mean diameter of 81.3 ± 1.3 nm were prepared by the solvent-evaporation-induced self-assembly. The physicochemical properties of tacrolimus loaded mPEG-b-PLGA micelles were evaluated, and the in vitro release behavior, degradation, cytotoxicity and bio-safety were all assessed. The ex vivo permeation of tacrolimus using rabbit corneas was also performed, and the cumulative permeation amount of tacrolimus from mPEG-b-PLGA micelles was significantly higher than 0.05% tacrolimus eye drops (p < 0.05). These results indicated that the formulations were feasible for intraocular drug delivery. Compared with 0.05% tacrolimus eye drops, the in vivo immunofluorescence analysis indicated the tacrolimus loaded mPEG-b-PLGA micelles remarkably inhibit the immune rejection after corneal allograft, with the lower expression levels of nuclear factor of activated T cells (NFAT), cluster of differentiation 4 (CD4) and cluster of differentiation 8 (CD8). In conclusion, we provided evidences that tacrolimus loaded mPEG-b-PLGA micelles would be a promising treatment for immune rejection after corneal transplantation.

Keywords: Anti-immune rejection; Ocular drug delivery; Polymeric micelles; Tacrolimus.

MeSH terms

  • Animals
  • Cell Survival / drug effects
  • Cornea / metabolism
  • Drug Carriers / administration & dosage*
  • Drug Carriers / chemistry
  • Drug Liberation
  • Female
  • Graft Rejection / drug therapy*
  • Immunosuppressive Agents / administration & dosage*
  • Immunosuppressive Agents / chemistry
  • Keratoplasty, Penetrating*
  • Male
  • Micelles*
  • Nanoparticles / administration & dosage*
  • Nanoparticles / chemistry
  • Polyesters / administration & dosage*
  • Polyesters / chemistry
  • Polyethylene Glycols / administration & dosage*
  • Polyethylene Glycols / chemistry
  • Rabbits
  • Rats, Sprague-Dawley
  • Rats, Wistar
  • Tacrolimus / administration & dosage*
  • Tacrolimus / chemistry

Substances

  • Drug Carriers
  • Immunosuppressive Agents
  • Micelles
  • Polyesters
  • methoxypolyethyleneglycol-poly(lactic-co-glycolic acid)
  • Polyethylene Glycols
  • Tacrolimus