Interfacial contacts within electrodes largely affect electronic transport and ion migration. Nanoscale electrode materials can achieve high reactivity, but their large interfacial contact areas lead to unavoidable impedance. Herein, a Ti3C2Tx MXene was used to construct a hybrid three-dimensional electrode material with a bilayer feature via a two-step vacuum filtration process. The introduced MXene flakes contributed to the electrode capacity, increased the electronic/ionic conductivity as a conductor and current collector, and enhanced the mechanical behaviour of the electrode by acting as a substrate. Such bilayer hybrid electrode design achieved promising cycling stability, and unlock an electrode architecture that can be applied to a wide range of two-dimensional materials.