A light-emitting molecular triad (BPCP-2CPC) with dual functionality was successfully synthesized and applied to solution-processed non-doped organic light-emitting diodes. The BPCP-2CPC triad contains 9-phenyl-9H-carbazole units as a host moiety tethered to a green-emitting core (BPCP) through a cyclohexane unit and exhibits thermally activated delayed fluorescence (TADF) and aggregation-induced emission (AIE) characteristics simultaneously. The BPCP-2CPC-based non-doped TADF-OLED devices showed a high external quantum efficiency (EQE) of 13.4%.