Aureonitols A and B, Two New C13 -Polyketides from Chaetomium globosum, an Endophytic Fungus in Salvia miltiorrhiza

Chem Biodivers. 2019 Sep;16(9):e1900364. doi: 10.1002/cbdv.201900364. Epub 2019 Sep 6.

Abstract

Two new C13 -polyketides, aureonitols A and B (1 and 2), along with five known compounds (3-7), were isolated from the solid fermentation culture of the plant endophytic fungus Chaetomium globosum from the aerial parts of Salvia miltiorrhiza. The structures and absolute configurations of 1 and 2 were determined by comprehensive spectroscopic data analysis and computed methods. Compound 5 was found to display the remarkable antimicrobial activities against four multidrug-resistant bacteria (Enterococcus faecalis, Enterococcus faecium, Staphylococcus aureus, and Staphylococcus epidermidis) with MIC values of 3.13-6.25 μg/mL (ciprofloxacin: 0.78-1.56 μg/mL), and also against all tested fungal strains with MIC values of 3.13-25 μg/mL (ketoconazole: 0.78-12.50 μg/mL).

Keywords: Chaetomium globosum; Salvia miltiorrhiza; antimicrobial activities; polyketides.

MeSH terms

  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / isolation & purification
  • Anti-Bacterial Agents / pharmacology*
  • Chaetomium / chemistry*
  • Chaetomium / metabolism
  • Dose-Response Relationship, Drug
  • Enterococcus faecalis / drug effects
  • Enterococcus faecium / drug effects
  • Fermentation
  • Furans / chemistry
  • Furans / isolation & purification
  • Furans / pharmacology*
  • Microbial Sensitivity Tests
  • Molecular Conformation
  • Polyketides / chemistry
  • Polyketides / isolation & purification
  • Polyketides / pharmacology*
  • Salvia miltiorrhiza / chemistry*
  • Staphylococcus aureus / drug effects
  • Staphylococcus epidermidis / drug effects

Substances

  • Anti-Bacterial Agents
  • Furans
  • Polyketides
  • aureonitol B