Bi spheres SPR-coupled Cu₂O/Bi₂MoO₆ with hollow spheres forming Z-scheme Cu₂O/Bi/Bi₂MoO₆ heterostructure for simultaneous photocatalytic decontamination of sulfadiazine and Ni(II)

Environmental problem on the coexistence of organic pollutants and heavy metals in surface waters has become increasingly serious. Few relative researches have focused on their simultaneous decontamination. Herein, a ternary plasmonic Z-scheme Cu₂O/Bi/Bi₂MoO₆ heterojunction was synthesized via two-step route followed by a wet-impregnation, where Bi spheres coupled with Cu₂O particles were anchored on the surface of Bi₂MoO₆ with hollow microflower spheres. The composites were characterized via various measurements. The excellent photocatalytic activity of Cu₂O/Bi/Bi₂MoO₆ displayed in single sulfadiazine (SDZ) oxidation or Ni(II) reduction, and their simultaneous removal. The degradation pathway for SDZ was investigated via LC-MS and Gaussian theory. DFT and FDTD calculations confirmed the electronic structural characteristics in the Cu₂O/Bi/Bi₂MoO₆ heterostructure and the induced electric field enhancement around nearly touching Bi spheres. A possible photodegradation mechanism of the as-prepared photocatalyst was elucidated via combining scavenger experiments with EPR technique. The results suggested h⁺, •O₂^- and •OH all participated in SDZ oxidation, which verified that Z-Scheme electron transfer was major manner in Cu₂O/Bi/Bi₂MoO₆, while •O₂^- and e^-acted on Ni(II) reduction. The improved photocatalytic activity of Cu₂O/Bi/Bi₂MoO₆ could be ascribed to the unique Z-scheme electron transfer among Cu₂O, Bi and Bi₂MoO₆, particularly SPR and local electric field near Bi spheres.