Engineering Bimetal Synergistic Electrocatalysts Based on Metal-Organic Frameworks for Efficient Oxygen Evolution

Benefiting from metal-organic frameworks (MOFs) unique structural characteristics, their versatility in composition and structure has been well explored in electrochemical oxygen evolution reaction (OER) processes. Here, a ligand/ionic exchange phenomenon of MOFs is reported in alkaline solution due to their poor stability, and the active species and reaction mechanism of MOFs are revealed in the OER process. A series of mixed Ni-MOFs and Fe-MOFs are synthesized by straightforward sonication and then directly used as catalyst candidates for OER in alkaline electrolyte. It can be confirmed via ex situ transmission electron microscopic images and X-ray diffraction patterns analysis, that the bimetallic hydroxide (NiFe-LDH) is generated in 1.0 m KOH in situ and acts as protagonist for oxygen evolution. The optimized catalyst (FN-2) exhibits a lower overpotential (275 mV at a current density of 10 mA cm^-2 ) and excellent long-term stability (strong current density for 100 h without fading). The revelation of the real active species of MOF materials may contribute to better understanding of the reaction mechanism.