Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it

Oleg S Morozov; Boris A Bulgakov; Anna V Ivanchenko; Svetlana S Shachneva; Sergey S Nechausov; Maxim V Bermeshev; Alexey V Kepman

doi:10.1016/j.dib.2019.104626

Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it

Data Brief. 2019 Oct 7:27:104626. doi: 10.1016/j.dib.2019.104626. eCollection 2019 Dec.

Authors

Oleg S Morozov¹, Boris A Bulgakov¹, Anna V Ivanchenko¹, Svetlana S Shachneva², Sergey S Nechausov¹, Maxim V Bermeshev³, Alexey V Kepman¹

Affiliations

¹ Lomonosov Moscow State University, Department of Chemistry, 119991, Leninskie Gory, 1-3, Moscow, Russia.
² Lomonosov Moscow State University, Faculty of Materials Science, 119991, Leninskie Gory, 1-73, Moscow, Russia.
³ A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Leninskiy prosp. 29, Moscow, Russia.

Abstract

This article describes data on preparation of sulfonated hydrogenated poly(phenylnorbornene) with different cations synthesized via sequential ring-opening metathesis polymerization, reduction, homogeneous sulfonation and cation exchange reactions. The data of the characterization of new polymers by nuclear magnetic resonance (¹H NMR) spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) are presented. The effect of imidazolium and 1-methylimidazolium cations, ionic liquid and Zwitter-type ion liquid on ionic conductivities evaluated by impedance spectroscopy. Preparation procedure of polymer electrolyte membrane based on new polymers and Nafion as a blend with polyvinylidene fluoride (PVDF) is given. Scanning electron microscopy images and ionic conductivities of these membrane are presented.

Keywords: Ionic conductivity; Ionic liquids; Ionomer; Polyelectrolyte membrane; Sulfonated polymer.