Dual responsive magnetic Fe₃O₄-TiO₂/graphene nanocomposite as an artificial nanozyme for the colorimetric detection and photodegradation of pesticide in an aqueous medium

The Fe₃O₄-TiO₂/reduced graphene oxide (Fe₃O₄-TiO₂/rGO) nanocomposite was successfully prepared by one step hydrothermal method and exhibit intrinsic peroxidase mimic activity and photocatalytic efficiency. The as-prepared nanomaterials were characterized by several analytical tools including XRD, HRTEM, FESEM, XPS, VSM, FT-IR, AFM, TGA and zeta potential analysis. The average particle size of Fe₃O₄ and TiO₂ NPs on the rGO nanosheets are found to be 9 ± 0.2 nm. The synthesized nanocomposite showed dual responsive including highly sensitive colorimetric detection of harmful atrazine pesticide in an aqueous medium as well as photocatalytic degradation of atrazine pesticide. The Fe₃O₄-TiO₂/rGO nanocomposite showed the efficient peroxidase-like catalytic activity throughout the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) as a peroxidase substrate to the blue-colored oxidized product (ox-TMB) in presence of H₂O₂. Based on this observation, the colorimetric detection technique is applied for the sensing of atrazine as model pesticides using TMB as a peroxidase substrate molecule and 2.98 μg/L of the limit of detection (LOD) was obtained in the linear range of 2-20 μg/L. Thus the proposed colorimetric sensing technique is simple and low cost for the real-time monitoring of the pesticides in an aqueous medium. Further, the Fe₃O₄-TiO₂/rGO nanocomposite was also successfully utilized towards efficient photocatalytic degradation of atrazine molecule (100 %) under irradiation of natural sunlight. Moreover, Fe₃O₄-TiO₂/rGO nanocomposite was successfully recycled for 10 times without a significant loss of its photocatalytic efficiency. This work delivers a new insight for the dual responsive of the Fe₃O₄-TiO₂/rGO nanocomposite as an artificial nanozyme for colorimetric sensing of the water pollutant and also removal of the water pollutant by simple photocatalytic degradation method under natural sunlight irradiation.