Abstract
HSP27 is highly expressed in, and supports oncogene addiction of, many cancers. HSP27 phosphorylation is a limiting step for activation of this protein and a target for inhibition, but its highly disordered structure challenges rational structure-guided drug discovery. We performed multistep biochemical, structural, and computational experiments to define a spherical 24-monomer complex composed of 12 HSP27 dimers with a phosphorylation pocket flanked by serine residues between their N-terminal domains. Ivermectin directly binds this pocket to inhibit MAPKAP2-mediated HSP27 phosphorylation and depolymerization, thereby blocking HSP27-regulated survival signaling and client-oncoprotein interactions. Ivermectin potentiated activity of anti-androgen receptor and anti-EGFR drugs in prostate and EGFR/HER2-driven tumor models, respectively, identifying a repurposing approach for cotargeting stress-adaptive responses to overcome resistance to inhibitors of oncogenic pathway signaling.
Keywords:
Drug therapy; Oncology.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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A549 Cells
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Animals
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Heat-Shock Proteins* / antagonists & inhibitors
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Heat-Shock Proteins* / chemistry
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Heat-Shock Proteins* / genetics
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Heat-Shock Proteins* / metabolism
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Humans
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Intracellular Signaling Peptides and Proteins / chemistry
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Intracellular Signaling Peptides and Proteins / genetics
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Intracellular Signaling Peptides and Proteins / metabolism
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Ivermectin* / chemistry
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Ivermectin* / pharmacology
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Mice
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Molecular Chaperones* / antagonists & inhibitors
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Molecular Chaperones* / chemistry
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Molecular Chaperones* / genetics
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Molecular Chaperones* / metabolism
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Neoplasms, Experimental* / drug therapy
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Neoplasms, Experimental* / genetics
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Neoplasms, Experimental* / metabolism
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Neoplasms, Experimental* / pathology
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Protein Domains
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Protein Multimerization
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Protein Serine-Threonine Kinases / chemistry
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Protein Serine-Threonine Kinases / genetics
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Protein Serine-Threonine Kinases / metabolism
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Receptor, ErbB-2* / genetics
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Receptor, ErbB-2* / metabolism
Substances
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HSPB1 protein, human
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Heat-Shock Proteins
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Intracellular Signaling Peptides and Proteins
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Molecular Chaperones
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Ivermectin
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MAP-kinase-activated kinase 2
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ERBB2 protein, human
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Receptor, ErbB-2
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Protein Serine-Threonine Kinases