VGLUT substrates and inhibitors: A computational viewpoint

Biochim Biophys Acta Biomembr. 2020 Dec 1;1862(12):183175. doi: 10.1016/j.bbamem.2020.183175. Epub 2020 Jan 7.

Abstract

The vesicular glutamate transporters (VGLUTs) bind and move glutamate (Glu) from the cytosol into the lumen of synaptic vesicles using a H+-electrochemical gradient (ΔpH and Δψ) generated by the vesicular H+-ATPase. VGLUTs show very low Glu binding and to date, no three-dimensional structure has been elucidated. Prior studies have attempted to identify the key residues involved in binding VGLUT substrates and inhibitors using homology models and docking experiments. Recently, the inward and outward oriented crystal structures of d-galactonate transporter (DgoT) emerged as possible structure templates for VGLUT. In this review, a new homology model for VGLUT2 based on DgoT has been developed and used to conduct docking experiments to identify and differentiate residues and binding orientations involved in ligand interactions. This review describes small molecule-ligand interactions including docking using a VGLUT2 homology model derived from DgoT.

Keywords: Docking; Glutamate; Homology models; Inhibitor; Substrate; Vesicular glutamate transporter.

Publication types

  • Research Support, N.I.H., Extramural
  • Review

MeSH terms

  • Binding Sites
  • Calcium-Binding Proteins / chemistry
  • Calcium-Binding Proteins / metabolism
  • Glutamic Acid / analogs & derivatives
  • Glutamic Acid / metabolism
  • Humans
  • Molecular Docking Simulation*
  • Monosaccharide Transport Proteins / chemistry
  • Monosaccharide Transport Proteins / metabolism
  • Periplasmic Binding Proteins / chemistry
  • Periplasmic Binding Proteins / metabolism
  • Protein Isoforms / antagonists & inhibitors
  • Protein Isoforms / metabolism
  • Substrate Specificity
  • Thermodynamics
  • Vesicular Glutamate Transport Proteins / antagonists & inhibitors
  • Vesicular Glutamate Transport Proteins / metabolism*

Substances

  • Calcium-Binding Proteins
  • Monosaccharide Transport Proteins
  • Periplasmic Binding Proteins
  • Protein Isoforms
  • Vesicular Glutamate Transport Proteins
  • galactose-binding protein
  • Glutamic Acid