Observe while it happens: catching photoactive proteins in the act with non-adiabatic molecular dynamics simulations

Curr Opin Struct Biol. 2020 Apr:61:106-112. doi: 10.1016/j.sbi.2019.12.013. Epub 2020 Jan 9.

Abstract

Organisms use photo-receptors to react to light. The first step is usually the absorption of a photon by a prosthetic group embedded inside the photo-receptor, often a conjugated chromophore. The electronic changes in the chromophore induced by photo-absorption can trigger a cascade of structural or chemical transformations that culminate into a response to light. Understanding how these proteins have evolved to mediate their activation process has remained challenging because the required time and spacial resolutions are notoriously difficult to achieve experimentally. Therefore, mechanistic insights into photoreceptor activation have been predominantly obtained with computer simulations. Here we briefly outline the challenges associated with such computations and review the progress made in this field.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Bacterial Proteins / chemistry
  • Bacterial Proteins / radiation effects
  • Crystallography, X-Ray
  • Light
  • Light-Harvesting Protein Complexes / metabolism
  • Molecular Dynamics Simulation*
  • Protein Conformation / radiation effects*
  • Proteins / chemistry*
  • Proteins / radiation effects*
  • Quantum Theory
  • Spectrum Analysis
  • Structure-Activity Relationship

Substances

  • Bacterial Proteins
  • Light-Harvesting Protein Complexes
  • Proteins