Synthesis of High Dimensionally Structured Mo-Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

Kosuke Shimoda; Satoshi Ishikawa; Masaya Tashiro; Masahiro Kumaki; Norihito Hiyoshi; Wataru Ueda

doi:10.1021/acs.inorgchem.9b03713

Synthesis of High Dimensionally Structured Mo-Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

Inorg Chem. 2020 Apr 20;59(8):5252-5255. doi: 10.1021/acs.inorgchem.9b03713. Epub 2020 Mar 30.

Authors

Kosuke Shimoda¹, Satoshi Ishikawa¹, Masaya Tashiro², Masahiro Kumaki¹, Norihito Hiyoshi³, Wataru Ueda¹

Affiliations

¹ Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1, Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan.
² Institute for Catalysis, Hokkaido University, N-21, W-10, Sapporo 001-0021, Japan.
³ National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai 983-8551, Japan.

PMID: 32223149
DOI: 10.1021/acs.inorgchem.9b03713

Abstract

High-dimensionally structured Mo-Fe oxide (HDS-MoFeO) was synthesized through an assembly of structural units supplied from Keplerate-type polyoxometalate, {Mo₇₂Fe₃₀}, under an appropriate hydrothermal condition. HDS-MoFeO showed excellent catalytic activity for the selective oxidation of methanol with slightly lower selectivity for formaldehyde than that of a conventional Mo-Fe oxide catalyst.