The Electron Cyclotron Resonance (ECR) Charge Breeding (CB) technique consists in transforming the charge state of an input beam from 1+ to n+ to allow post-acceleration. The optimization of an ECR-CB requires a deep investigation of ion dynamics and electron heating, the latter being influenced by the microwave-to-plasma coupling mechanism. In this paper, we report the electromagnetic analysis of the microwave-to-plasma coupling of the Selective Production of Exotic Species charge breeder (SPES-CB) plasma chamber, taking into account the presence of the plasma through its dielectric tensor, performed using a self-consistent approach. In particular, the effect of two different frequencies on the plasma-wave interaction will be shown, in terms of electromagnetic properties such as plasma-absorbed power, giving numerical evidence of the frequency tuning effect.