Bile acids, lipid and purine metabolism involved in hepatotoxicity of first-line anti-tuberculosis drugs

Expert Opin Drug Metab Toxicol. 2020 Jun;16(6):527-537. doi: 10.1080/17425255.2020.1758060. Epub 2020 May 21.

Abstract

Objectives: Rifampin (RIF), isoniazid (INH) and pyrazinamide (PZA) are essential components of the short-term first-line anti-tuberculosis (anti-TB) chemotherapy regimen and can cause hepatotoxicity. However, the mechanism of anti-TB drug-induced hepatotoxicity (ATDH) is currently unclear. We investigate the relevant contributions to liver injury and the pathway of the above-mentioned drugs administered alone or in combination.

Methods: UPLC-Q-TOF/MS-based metabolomics, bile acids (BAs) analysis and FXR/SHP detection were used to evaluate the toxicity of these drugs and clarify the underlying metabolism-related pathway.

Results: In C57BL/6 mice administered the corrected clinical doses, RIF, INH and PZA could induced hepatotoxicity; with less toxicity in the combination therapy than RIF. The pathological biochemistry, BAs concentration and metabolically regulated FXR/SHP gene expression analyzes in mice were consistent with the metabolomics results. FXR played a role in the hepatotoxicity of anti-tuberculosis drugs in the obeticholic acid treated and FXR-/- mice. Additionally, the purine and lipid metabolic pathways were involved in ATDH.

Conclusion: ATDH was involved in bile acids and lipid and purine metabolism. The BAs metabolic pathway involvement in mice was validated in TB patients. The noninvasive metabolomics approach is more systemic than routine toxicity evaluation and can be used to assess compound toxicity and the underlying mechanism.

Keywords: FXR; Metabolomics; bile acid; first-line anti-tuberculosis drugs; hepatotoxicity.

MeSH terms

  • Animals
  • Antitubercular Agents / administration & dosage
  • Antitubercular Agents / toxicity*
  • Bile Acids and Salts / metabolism
  • Chemical and Drug Induced Liver Injury / etiology*
  • Chemical and Drug Induced Liver Injury / physiopathology
  • Chromatography, High Pressure Liquid
  • Drug Therapy, Combination
  • Isoniazid / administration & dosage
  • Isoniazid / toxicity
  • Lipid Metabolism / drug effects
  • Male
  • Mass Spectrometry
  • Metabolomics
  • Mice
  • Mice, Inbred C57BL
  • Mice, Knockout
  • Purines / metabolism
  • Pyrazinamide / administration & dosage
  • Pyrazinamide / toxicity
  • Receptors, Cytoplasmic and Nuclear / genetics*
  • Rifampin / administration & dosage
  • Rifampin / toxicity

Substances

  • Antitubercular Agents
  • Bile Acids and Salts
  • Purines
  • Receptors, Cytoplasmic and Nuclear
  • farnesoid X-activated receptor
  • Pyrazinamide
  • Isoniazid
  • Rifampin