A Broccoli aptamer chimera yields a fluorescent K+ sensor spanning physiological concentrations

Chem Commun (Camb). 2021 Feb 7;57(11):1344-1347. doi: 10.1039/d0cc07042d. Epub 2021 Jan 12.

Abstract

The RNA aptamer Broccoli accepts 2'fluorinated (2'F) pyrimidine nucleotide incorporation without perturbation of structure or fluorescence in the presence of potassium and DFHBI. However, the modification decreases Broccoli's apparent affinity for K+ >30-fold. A chimera of Broccoli RNAs with mixed chemistries displays linear fluorescent gain spanning physiological K+ concentrations, yielding an effective RNA-based fluorescent K+ sensor.

MeSH terms

  • Aptamers, Nucleotide / chemistry*
  • Fluocinolone Acetonide
  • Fluorescence
  • Fluorescent Dyes / chemistry
  • HEK293 Cells
  • Humans
  • Nucleic Acid Conformation
  • Potassium / chemistry*
  • RNA / chemistry

Substances

  • Aptamers, Nucleotide
  • Fluorescent Dyes
  • Fluocinolone Acetonide
  • RNA
  • Potassium