New Advanced Glycation End Products Observed in Rat Urine by Untargeted Metabolomics after Feeding with Heat-Treated Skimmed Milk Powder

Mol Nutr Food Res. 2021 Apr;65(7):e2001049. doi: 10.1002/mnfr.202001049. Epub 2021 Mar 3.

Abstract

Scope: Milk powder is commonly consumed throughout the world. However, advanced glycation end products (AGEs) will form in milk powder during thermal processing and long-term storage. This study aimed to identify such compounds with potential as new urinary biomarkers of intake of heat-treated skimmed milk powder (HSMP).

Methods and results: A parallel study is performed with different dosages of HSMP as well as hydrolyzed HSMP and untreated skimmed milk powder (SMP) in 36 rats. The 24-h urine samples on day 7 or 8 are collected and profiled by untargeted UPLC-Qtof-MS metabolomics. Statistical analysis revealed 25 metabolites differentiating SMP and HSMP; nineteen of these structures are proposed as lysine- and arginine-derived AGEs, and heterocyclic compounds.

Conclusion: These metabolites may potentially serve as biomarkers of food intake pending further validation to assess intakes of heat-processed dairy foods and thus help to elucidate the effects of HSMP consumption or dietary AGEs on human health.

Keywords: Maillard reaction; advanced glycation end products; biomarker; metabolomics; skimmed milk powder.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Arginine / chemistry
  • Biomarkers / urine*
  • Glycation End Products, Advanced / chemistry
  • Glycation End Products, Advanced / metabolism
  • Glycation End Products, Advanced / urine*
  • Heating
  • Lysine / chemistry
  • Male
  • Metabolomics / methods
  • Milk* / chemistry
  • Powders
  • Rats
  • Rats, Sprague-Dawley

Substances

  • Biomarkers
  • Glycation End Products, Advanced
  • Powders
  • Arginine
  • Lysine