Visible-Light-Induced Photocatalytic Oxidative Decarboxylation of Cinnamic Acids to 1,2-Diketones

Shiv Chand; Anand Kumar Pandey; Rahul Singh; Krishna Nand Singh

doi:10.1021/acs.joc.1c00322

Visible-Light-Induced Photocatalytic Oxidative Decarboxylation of Cinnamic Acids to 1,2-Diketones

J Org Chem. 2021 May 7;86(9):6486-6493. doi: 10.1021/acs.joc.1c00322. Epub 2021 Apr 14.

Authors

Shiv Chand¹, Anand Kumar Pandey¹, Rahul Singh¹, Krishna Nand Singh¹

Affiliation

¹ Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India.

PMID: 33851837
DOI: 10.1021/acs.joc.1c00322

Abstract

A concerted metallophotoredox catalysis has been realized for the efficient decarboxylative functionalization of α,β-unsaturated carboxylic acids with aryl iodides in the presence of perylene bisimide dye to afford 1,2-diketones.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carboxylic Acids*
Catalysis
Decarboxylation
Molecular Structure
Oxidation-Reduction
Oxidative Stress*

Substances

Carboxylic Acids