Two new sesquiterpenoid lactone derivatives from Lindera aggregata

Nat Prod Res. 2022 Nov;36(21):5407-5415. doi: 10.1080/14786419.2021.1939332. Epub 2021 Jun 18.

Abstract

Two new sesquiterpenoid lactone derivatives, linderin A (1) and linderin B (2) comprising a sesquiterpenoid lactone and a methyl geranylhomogentisate moiety together with six known compounds were isolated from the roots of Lindera aggregata. Their chemical structures were elucidated using extensive spectroscopic analysis including 1 D, 2 D NMR, and HR-ESI-MS data and compared with previously reported data. The absolute configurations of 1 and 2 were assigned based on the electronic circular dichroism calculation. Compound 2 showed moderate anticoagulant activity.

Keywords: Lindera aggregata; anticoagulant; electronic circular dichroism; sesquiterpenoid.

MeSH terms

  • Lactones / chemistry
  • Lindera* / chemistry
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Plant Roots / chemistry
  • Sesquiterpenes* / chemistry

Substances

  • Lactones
  • Sesquiterpenes