Untargeted serum metabolomics and tryptophan metabolism profiling in type 2 diabetic patients with diabetic glomerulopathy

Ren Fail. 2021 Dec;43(1):980-992. doi: 10.1080/0886022X.2021.1937219.

Abstract

Diabetic glomerulopathy (DG) remains the prevalent microvascular complication and leading cause of shortened lifespan in type-2 diabetes mellitus (T2DM) despite improvement in hyperglycemia control. Considering the pivotal role of kidney in metabolism, using untargeted metabolomic techniques to globally delineate the serum metabolite profiles will help advance understanding pathogenetic underpinnings of renal biopsy-confirmed DG from the perspective of metabolism specifically. Fourteen pathologically diagnosed DG patients secondary to T2DM and 14 age- and gender-matched healthy controls (HCs) were recruited for study. We employed mass spectrometry-based untargeted metabolomic methods to reveal the metabolite profiles of serum samples collected from all included subjects. We identified a total of 334 and 397 metabolites in positive and negative ion mode respectively. One hundred and eighty-two important differential metabolites whose variable importance in projection (VIP) > 1 and p value <0.05 were selected and annotated to metabolic pathways. KEGG pathway enrichment analysis revealed tryptophan metabolism enriched most significantly. Among the tryptophan derivatives, L-tryptophan (L-Trp) and serotonin were relatively accumulated in DGs compared with HCs, while 5-hydroxyindoleacetic acid (5-HIAA) and indole-3-acetamide were depleted. Correlation analysis showed serotonin and L-Trp are negatively correlated with 24 h urine protein and glycosylated hemoglobin (Ghb). To exclude the interference of preexisting T2DM on DG exacerbation, we selected 5-HIAA and 3-(3-hydroxyphenyl) propionic acid (3-OHPPA) which are not correlated with Ghb and analyzed their correlation relationship with crucial renal indices. We found 3-OHPPA is positively correlated with urine total protein and creatinine ratio (T/Cr) and 24 h urine protein, 5-HIAA is positively correlated with serum creatinine and urea.

Keywords: Diabetic glomerulopathy; mechanism; serum metabolites; untargeted metabolomics.

MeSH terms

  • Adult
  • Case-Control Studies
  • Creatinine / blood
  • Creatinine / urine
  • Diabetes Mellitus, Type 2 / complications*
  • Diabetic Nephropathies / blood*
  • Diabetic Nephropathies / urine*
  • Female
  • Humans
  • Linear Models
  • Male
  • Metabolic Networks and Pathways
  • Metabolomics / methods*
  • Middle Aged
  • Tryptophan / metabolism*

Substances

  • Tryptophan
  • Creatinine

Grants and funding

This work was supported by the National Natural Science Foundation of China [Grant Nos. 81873611 and 81700633], Science and Technology Innovation Team of Henan [Grant No. 17IRTSTHN020], 2020 Key Project of Medical Science and Technology [Grant No. SBGJ202002056]; Foundation for Leading Personnel of Central Plains of China [Grant No. 194200510006]. All of the human samples were stored in the Biobank of The First Affiliated Hospital of Zhengzhou University and National Human Genetic Resources Sharing Service Platform [Grant No. 2005DKA21300].