Herein, we disclose a recyclable, hybrid manganese catalyst for site-selective azine C-H activation by weak amide assistance. The novel, reusable catalyst enabled C3-H arylation and C3-H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.
Keywords: C−H alkylation; C−H arylation; hybrid catalysis; manganese catalysis; site-selectivity.
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