Selective recovery of phosphorus and urea from fresh human urine using a liquid membrane chamber integrated flow-electrode electrochemical system

Phosphorus (P) extraction from human urine is a potential strategy to address global resource shortage, but few approaches are able to obtain high-quality liquid P products. In this study, we introduced an innovative flow-electrode capacitive deionization (FCDI) system, also called ion-capture electrochemical system (ICES), for selectively extracting P and N (i.e., urea) from fresh human urine simply by integrating a liquid membrane chamber (LMC) using a pair of anion exchange membrane (AEM). In the charging process, negatively charged P ions (i.e., HPO₄^2- and H₂PO₄^-) can be captured by acidic extraction solutions (e.g., solutions of HCl, HNO₃ and H₂SO₄) on their way to the anode chamber, leading to the conversion of P ions to uncharged H₃PO₄, while other undesired ions such as Cl^- and SO₄^2- are expelled. Simultaneously, uncharged urea molecules remain in the urine effluent with the removal of salt. Thus, high-purity phosphoric acid and urea solutions can be obtained in the LMC and spacer chambers, respectively. The purification of P in an acidic environment is ascribed largely to the competitive migration and protonation of ions. The latter contributes ~27% for the selective capture of P. Under the optimal operating conditions (i.e., ratio of the urine volume to the HCl volume = 7:3, initial pH of the extraction solution = 1.43, current density = 20 A/m² and threshold pH ~ 2.0), satisfactory recovery performance (811 mg/L P with 73.85% purity and 8.3 g/L urea-N with 81.4% extraction efficiency) and desalination efficiency (91.1%) were obtained after 37.5 h of continuous operation. Our results reveal a promising strategy for improving in selective separation and continuous operation via adjustments to the cell configuration, initiating a new research dimension toward selective ion separation and high-quality P recovery.