A novel SPR based Fe@Ag core-shell nanosphere entrapped on starch matrix an optical probe for sensing of mercury(II) ion: A nanomolar detection, wide pH range and real water sample application

Recent trends in nanotechnology paved a way for the development of detection systems for heavy metals, toxins and environmental pollutants. The present study focused on Hg²⁺ detection by a core shell Fe@Ag-starch nanosphere phenylalanine conjugate. The characterization of core shell Fe@Ag-starch nanosphere was performed by using TEM, zetasizer, particlesize analyzer, UV-visible absorption spectrophotometer, EDAX, FTIR and TGA. The NPs showed λmax at 408 nm. The effective diameter of synthesized nanosphere was 37 ± 2 nm and it possessed the surfaces charge of -36.12 ± 2.5 mV. The Fe@Ag-starch-phenylalanine conjugate reacted with Hg²⁺, the yellow colour of the nanosphere phenylalanine conjugate became colourless. The real water sample was collected and the amount of Hg²⁺ was calculated by using the prepared nanosphere. The detection of Hg²⁺ at different conditions including various saline concentrations, temperature and pH were also studied and the detection was found to be effective at 40 °C, pH 5 and 0.1% of saline concentration. The LOD of Hg²⁺ ions by Fe@Ag-starch nanosphere were calculated to be 1.84 nM. The influence of other metal ions present in the analyte did not show any interference on Hg²⁺ detection. In addition, the photocatalytic and antibacterial activities of Fe@Ag-starch nanosphere were also studied. The study confirmed that the core shell nanosphere can also be used for environmental cleanup and disinfection.